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tert-Butyldichlorophosphine

Catalog Number
ACM25979071-2
Product Name
tert-Butyldichlorophosphine
Structure
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CAS
25979-07-1
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Synonyms
CTK4F6872; AN-5752; tert-Butyldichlorophosphine solution, 1.0 M in diethyl ether; tert-Butylphosphine dichloride; DTXSID00180639; O529; Phosphonous dichloride, (1,1-dimethylethyl)-; Phosphonous dichloride,P-(1,1-dimethylethyl)-; SCHEMBL1456657; Phosphonous dichloride, P-(1,1-dimethylethyl)-;
IUPAC Name
tert-butyl(dichloro)phosphane;
Molecular Weight
158.99g/mol
Molecular Formula
C4H9Cl2P;
Canonical SMILES
CC(C)(C)P(Cl)Cl;
InChI
InChI=1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3;
InChI Key
NMJASRUOIRRDSX-UHFFFAOYSA-N;
Storage
Flammables area
Complexity
55.2
Covalently-Bonded Unit Count
1
EC Number
247-386-9
Exact Mass
157.982g/mol
Heavy Atom Count
7
Monoisotopic Mass
157.982g/mol
Topological Polar Surface Area
0A^2
Application
Tert-Butyldichlorophosphine, appearing as a white to light yellow crystalline powder, serves a vital role in the synthesis of alkali metal complexes. It is primarily utilized for preparing mono- and bidentate phosphine ligands in metal complexes, which are essential for catalytic chiral asymmetric hydrogenations and other asymmetric reactions, as well as for transition metal coupling reactions. Additionally, this reagent is employed in the preparation of various phosphines used in catalytic polymerization reactions.
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