t-BuDavePhos
Catalog Number
ACM224311493-2
Product Name
t-BuDavePhos
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/224311-49-3.gif)
CAS
224311-49-3
Synonyms
2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179;
IUPAC Name
2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline;
Molecular Weight
341.479g/mol
Molecular Formula
C22H32NP;
Canonical SMILES
CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2N(C)C)C(C)(C)C;
InChI
InChI=1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3;
InChI Key
PHLPNEHPCYZBNZ-UHFFFAOYSA-N;
Complexity
376
Covalently-Bonded Unit Count
1
Exact Mass
341.227g/mol
H-Bond Acceptor
1
Heavy Atom Count
24
Monoisotopic Mass
341.227g/mol
Rotatable Bond Count
5
Topological Polar Surface Area
3.2A^2
Application
t-BuDavePhos is a valuable ligand often used in various palladium-catalyzed reactions. It is particularly effective in facilitating carbon-oxygen bond formation, which is crucial in the Suzuki reaction. This ligand is also instrumental in the selective Pd-catalyzed arylation of ammonia, a key step in synthesizing dibenzodiazepines. Additionally, t-BuDavePhos plays a significant role in the selective silylation of aryl chlorides and enables Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to produce 1,4-enynes. Its versatility and effectiveness are evident in these applications, all thanks to its physical form as white crystals or a crystalline powder.
- CAS
- Size
- Purity
- Price
- Quantity
- Order
- 224311-49-3
- -
- -
- -
-
- +
-
Online Inquiry
※ Please kindly note that our products are for research use only.
(1R,2R)-2-Amino-1-phenylpropyldiphenylphosphine
(799297-44-2)
Tetraphenylphosphonium bromide
(2751-90-8)
(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
(35193-63-6)
(2-Carboxyethyl)triphenylphosphonium Bromide
(51114-94-4)
Tetraphenylphosphonium Iodide
(2065-67-0)
Tetraphenylphosphonium Chloride
(2001-45-8)
