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Silver hexafluorophosphate

Catalog Number
ACM26042637
Product Name
Silver hexafluorophosphate
Structure
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CAS
26042-63-7
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Synonyms
Phosphate(1-), hexafluoro-, silver(1+) (1:1)
IUPAC Name
Silver;hexafluorophosphate
Molecular Weight
252.83
Molecular Formula
AgPF6
Canonical SMILES
F[P-](F)(F)(F)(F)F.[Ag+]
InChI
InChI=1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1
InChI Key
SCQBROMTFBBDHF-UHFFFAOYSA-N
Melting Point
102 °C
Purity
99%+
Solubility
Soluble in organic solvents such as benzene, toluene, and acetonitrile
Appearance
Yellow to pale brown powder
Complexity
62.7
Covalently-Bonded Unit Count
2
EC Number
247-428-6
Exact Mass
251.86927
H-Bond Acceptor
7
Heavy Atom Count
8
Monoisotopic Mass
251.86927
Rotatable Bond Count
0
Topological Polar Surface Area
0 Ų
Application
Silver hexafluorophosphate, appearing as a white to greyish-beige powder, serves primarily as an oxidant in the formation of silver metal. Its applications extend into inorganic and organometallic chemistry, where it functions as a crucial reagent. This compound is integral in engineering novel materials and synthesizing supramolecular Ag(I) complexes. Furthermore, it plays a significant role in the development of new catalysts by substituting halide ligands with the weakly coordinating hexafluorophosphate anion.
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