NAVIGATION

Tel:
Fax:
Address:
Email: For product inquiries or a copy of our product catalog, please use our online system or send an email to .

(S)-(-)-TolBINAP

PRICE INQUIRY

Catalog Number

ACM100165886

Product Name

(S)-(-)-TolBINAP

Structure

CAS

100165-88-6

Product Overview
Usage

IUPAC Name

[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;

Molecular Weight

678.796g/mol

Molecular Formula

C48H40P2;

Canonical SMILES

CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C;

InChI

InChI=1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3;

InChI Key

IOPQYDKQISFMJI-UHFFFAOYSA-N;

Complexity

897

Covalently-Bonded Unit Count

Exact Mass

678.261g/mol

Heavy Atom Count

Monoisotopic Mass

678.261g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

Application

Useful ligand for palladium-catalyzed carbon-oxygen bond formation.

Ligand for palladium-catalyzed α-arylation of ketones.

Ligand for Cu-catalyzed asymmetric conjugate reduction.

Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.

Enantioselective conjugate reduction of lactones and lactams.

Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.

Catalytic Aldol reaction to ketones.

Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.

Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.

Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.

Rhodium-catalyzed cross cyclotrimerization.

If you have any other questions or need other size, please get a quote.

CAS
Size
Purity
Price
Quantity
Order

100165-88-6
-
-
-
- +
Online Inquiry

※ Please kindly note that our products are for research use only.

(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP* (1107608-80-9)
(R)-Tol-BINAP (99646-28-3)
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene (147253-67-6)
1,8-Bis(diphenylphosphino)naphthalene (153725-04-3)
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene (71042-55-2)
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane (129648-07-3)

Products

Chiral Catalysts
Ligands
Metal Catalysts
Non-Metal Catalysts
Organocatalysts
Phase Transfer Catalysts
Photocatalysts
Reaction Type

Interested in our Services & Products? Need detailed information?

Email:
Tel:
Fax:
Address: