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- (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine
PRICE INQUIRYCatalog Number
ACM185449803-1
Product Name
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/185449-80-3.gif)
CAS
185449-80-3
Synonyms
(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a; (S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine; AKOS015918434; A116070; (R)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine; N,N-Dimethyldinaphtho[2,1-d:1 inverted exclamation mark ,2 inverted exclamation mark -f][1,3,2]dioxaphosphepin-4-amine; AX8210337; ()-MonoPhos; BP-12203; S-MonoPhos;
IUPAC Name
N,N-dimethyl-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine;
Molecular Weight
359.365g/mol
Molecular Formula
C22H18NO2P;
Canonical SMILES
CN(C)P1OC2=C(C3=CC=CC=C3C=C2)C4=C(O1)C=CC5=CC=CC=C54;
InChI
InChI=1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3;
InChI Key
QCHAVHXSBZARBO-UHFFFAOYSA-N;
Complexity
461
Covalently-Bonded Unit Count
1
Exact Mass
359.108g/mol
H-Bond Acceptor
3
Heavy Atom Count
26
Monoisotopic Mass
359.108g/mol
Rotatable Bond Count
1
Topological Polar Surface Area
29.5A^2
Application
The purpose of (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine is to serve as a highly efficient ligand within the DSM MonoPhos family, facilitating the asymmetric hydrogenation of ketones and β-keto esters. This compound not only enhances the enantioselectivity of hydrogenation processes but also supports light-induced, enantioselective hydrogenation, making it a valuable tool in achieving high-efficiency reactions in synthetic chemistry.
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