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- (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
PRICE INQUIRYCatalog Number
ACM619334939-2
Product Name
(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/619334-93-9.gif)
CAS
619334-93-9
Synonyms
[Rh COD (S)-Xyl-Phanephos]BF4; 619334-93-9; [(R)-4,12-Bis[di(3,5-xylyl)phosphino][2.2]paracyclophane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; [Rh COD (R)-Xyl-Phanephos]BF4; [(S)-4,12-Bis[di(3,5-xylyl)phosphino][2.2]paracyclophane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;
IUPAC Name
[11-bis(3,5-dimethylphenyl)phosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-bis(3,5-dimethylphenyl)phosphane;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate;
Molecular Weight
986.769g/mol
Molecular Formula
C56H62BF4P2Rh-;
Canonical SMILES
[B-](F)(F)(F)F.CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C.C1CC=CCCC=C1.[Rh];
InChI
InChI=1S/C48H50P2.C8H12.BF4.Rh/c1-31-17-32(2)22-43(21-31)49(44-23-33(3)18-34(4)24-44)47-29-39-9-13-41(47)15-11-40-10-14-42(16-12-39)48(30-40)50(45-25-35(5)19-36(6)26-45)46-27-37(7)20-38(8)28-46;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-10,13-14,17-30H,11-12,15-16H2,1-8H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;;
InChI Key
APILCLFERIYDHA-ONEVTFJLSA-N;
Complexity
973
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
2
Exact Mass
986.341g/mol
Formal Charge
-1
H-Bond Acceptor
5
Heavy Atom Count
64
Monoisotopic Mass
986.341g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
0A^2
Application
The purpose of (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, with a minimum purity of 97%, is to serve as a catalyst for the enantioselective hydrogenation of unsaturated amino acid derivatives. This specialized compound is designed to facilitate the process of selectively adding hydrogen atoms to these specific derivatives, thereby enhancing the efficiency and precision of the reaction in producing desired chiral molecules.
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