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- (R)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
(R)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
PRICE INQUIRYCatalog Number
ACM1038932670
Product Name
(R)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
CAS
1038932-67-0
Synonyms
(S)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; [(S)-4,12-Bis[di(4-methoxyphenyl)phosphino][2.2]paracyclophane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; [Rh COD (S)-AnPhanephos]BF4, Rh 10.4%; [Rh COD (R)-AnPhanephos]BF4, Rh 10.4%; [(R)-4,12-Bis[di(4-methoxyphenyl)phosphino][2.2]paracyclophane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;
IUPAC Name
[11-bis(4-methoxyphenyl)phosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-bis(4-methoxyphenyl)phosphane;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate;
Molecular Weight
994.657g/mol
Molecular Formula
C52H54BF4O4P2Rh-;
Canonical SMILES
[B-](F)(F)(F)F.COC1=CC=C(C=C1)P(C2=CC=C(C=C2)OC)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC=C(C=C6)OC)C7=CC=C(C=C7)OC.C1CC=CCCC=C1.[Rh];
InChI
InChI=1S/C44H42O4P2.C8H12.BF4.Rh/c1-45-35-13-21-39(22-14-35)49(40-23-15-36(46-2)16-24-40)43-29-31-5-9-33(43)11-7-32-6-10-34(12-8-31)44(30-32)50(41-25-17-37(47-3)18-26-41)42-27-19-38(48-4)20-28-42;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-6,9-10,13-30H,7-8,11-12H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;;
InChI Key
OTNDHXHQSLLSTC-ONEVTFJLSA-N;
Complexity
946
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
2
Exact Mass
994.258g/mol
Formal Charge
-1
H-Bond Acceptor
9
Heavy Atom Count
64
Monoisotopic Mass
994.258g/mol
Rotatable Bond Count
10
Topological Polar Surface Area
36.9A^2
Application
(R)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, with a purity of at least 97%, serves as a catalyst designed to facilitate the efficient and enantioselective synthesis of β,β-disubstituted carboxylic acids. By leveraging its unique structure, this catalyst enhances reaction precision and selectivity, making it invaluable for producing these complex molecules with high enantiomeric purity.
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