CAS 68478-92-2 Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution

Synonyms

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution, 0.05 M in poly(dimethylsiloxane), vinyl terminated; MFCD00151662; AKOS015902689; Platinum-divinyltetramethyldisiloxane complex in vinyl term. polydimethylsiloxanes (1% Platinum); ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane,platinum; Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxanecomplex,soln.invinylterminatedpolydimethylsiloxane; Platinum-divinyltetramethyldisiloxane complex in vinyl terminated poly(dimethylsiloxane) (3-3.5%Pt); RTR-022885; SCHEMBL63112; Platinum-divinyltetramethyldisiloxane complex in vinyl terminated poly(dimethylsiloxane) (0.5%Pt);

IUPAC Name

ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane;platinum;

Molecular Weight

381.485g/mol

Molecular Formula

C8H18OPtSi2;

Canonical SMILES

C[Si](C)(C=C)O[Si](C)(C)C=C.[Pt];

InChI

InChI=1S/C8H18OSi2.Pt/c1-7-10(3,4)9-11(5,6)8-2;/h7-8H,1-2H2,3-6H3;;

InChI Key

RCNRJBWHLARWRP-UHFFFAOYSA-N;

Complexity

144

Covalently-Bonded Unit Count

EC Number

270-844-4

Exact Mass

381.054g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

381.054g/mol

Rotatable Bond Count

Topological Polar Surface Area

9.2A^2

Application

The Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution is a pale yellow liquid with a molecular formula of O[Si(CH3)2CH=CH2]2Pt and a molecular weight of 381.48, serving as a versatile organometallic compound in various scientific applications. This coordination complex of platinum(0) is instrumental in the synthesis of other organometallic compounds like gold(I)-DVTMDS and palladium(II)-DVTMDS. Its significance extends to facilitating essential chemical reactions, including the catalytic hydrogenation of aldehydes and ketones, as well as the oxidation of organic compounds. Additionally, it acts as a precursor in developing electrochemical systems, such as the Pt/SnO2 catalyst with a low metal load, and serves as a catalyst in creating phenol functional silanes for use as adhesion promoters. Known in the industry as Karstedt's catalyst, it is prominently used in hydrosilylation reactions, highlighting its critical role as a catalyst in both industrial and research settings.

January 28, 2025

Essential Catalyst for Advanced Research

The Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution is excellent for synthesizing organometallic compounds and facilitating catalytic hydrogenation and oxidation reactions. Its reliability in the lab is outstanding.