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(1,10-Phenanthroline)bis(triphenylphosphine)copper(I) nitrate dichloromethane adduct

(1,10-Phenanthroline)bis(triphenylphosphine)copper(I) nitrate dichloromethane adduct

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Catalog Number

ACM33989105-2

Product Name

Structure

CAS

33989-10-5

Product Overview
Usage

Synonyms

33989-10-5, SC10053, BIS COPPER NITRATEDICHLOROMETHANEADDUCT

IUPAC Name

copper(1+);dichloromethane;1,10-phenanthroline;triphenylphosphane;nitrate

Molecular Weight

915.26

Molecular Formula

[Cu(C12H8N2)[P(C6H5)3]2]NO3 · 1/2CH2Cl2

Canonical SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C(Cl)Cl.[N+](=O)([O-])[O-].[Cu+]

InChI Key

RMYGTLXCRLUAKL-UHFFFAOYSA-N

Purity

96%

Exact Mass

913.12200

H-Bond Acceptor

H-Bond Donor

Application

The purpose of (1,10-Phenanthroline)bis(triphenylphosphine)copper(I) nitrate dichloromethane adduct is to facilitate a variety of high-yield synthetic processes, serving as an effective catalyst in the formation of complex organic compounds. This copper(I) catalyst is instrumental in the coupling of o-iodophenols and aryl acetylenes, leading to the efficient production of 2-arylbenzo[b]furans. Additionally, it aids in the high-yield synthesis of vinyl sulfides, the efficient formation of 1,3-enynes, and the effective synthesis of 2-substituted indoles. The catalyst also supports the synthesis of 1,4-disubstituted 5-iodotriazoles and enables selective cyclization strategies for creating 2-substituted benzofurans and indoles. Furthermore, it promotes copper-catalyzed cascade reactions essential for producing 2-indolyl-C-glycosides.

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CAS
Size
Purity
Price
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33989-10-5
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96%
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