Synonyms
Bis(pentamethylcyclopentadienylrhodium dichloride)
Molecular Weight
618.07
Molecular Formula
C20H30Cl4Rh2
Purity
Rh ≥32.7%
Appearance
crimson powder
MDL Number
MFCD00061552
Symbol
GHS07
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- (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Catalog Number
ACM12354857-4
Product Name
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/12354-85-7.gif)
CAS
12354-85-7
Application
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer is a versatile burgundy solid catalyst employed in a wide range of chemical transformations. It plays a critical role in oxidative olefination reactions and facilitates C-C bond cleavage of secondary alcohols, leading to enhanced structural modification capabilities. This compound is integral to the ortho C-H olefination of phenol derivatives and the oxidative annulation of pyridines, enabling the generation of complex molecular architectures. Additionally, it supports the oxidative ortho-acylation of benzamides with aldehydes through direct sp2 C-H bond functionalization. Beyond these applications, it serves as a catalyst for amidation, reductive alkylation, and both hydrogenation and chiral hydrogenation reactions. Notably, it is effective in solventless conditions for acetanilide functionalization using a ball mill. The catalyst is also instrumental in the rhodium-catalyzed regioselective direct C-H arylation of indoles with aryl boronic acids, the asymmetric transfer hydrogenation of imines in water, and in facilitating the rhodium-catalyzed synthesis of fluorinated pyridines as well as the alkylation of azobenzenes with allyl acetates.
February 16, 2025
Exceptional Catalyst for Advanced Organic Syntheses
Using (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer as a catalyst significantly enhanced my oxidative olefination and C-H arylation research. Its effectiveness streamlined complex reaction pathways in my projects, demonstrating superior performance in synthesizing novel compounds.
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