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(Pentafluorophenyl)diphenylphosphine

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Catalog Number

ACM5525951-1

Product Name

Structure

CAS

5525-95-1

Product Overview
Usage

Synonyms

K-9881; PENTAFLUOROPHENYLDIPHENYLPHOSPHINE; ZINC95719251; KS-000014OH; ANW-32275; C-20669; CTK1H4461; VZ31949; NSC-175502; FT-0625245;

IUPAC Name

(2,3,4,5,6-pentafluorophenyl)-diphenylphosphane;

Molecular Weight

352.244g/mol

Molecular Formula

C18H10F5P;

Canonical SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C(=C(C(=C3F)F)F)F)F;

InChI

InChI=1S/C18H10F5P/c19-13-14(20)16(22)18(17(23)15(13)21)24(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H;

InChI Key

KUTXTUCJQJPJBH-UHFFFAOYSA-N;

Complexity

363

Covalently-Bonded Unit Count

Exact Mass

352.044g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

352.044g/mol

NSC Number

175502

Rotatable Bond Count

Topological Polar Surface Area

0A^2

Application

(Pentafluorophenyl)diphenylphosphine, a compound typically found in a white to light yellow crystal form, serves a fundamental purpose in the synthesis of complex chemical structures. When reacted with C-ethoxycarbonyl-(p-methoxyphenyl) nitrile imine, it aids in the creation of [2,3,4,5-tetrafluoro-6-(p-methoxyphenylamino)phenyl]diphenylphosphine oxide. This particular compound can then be further reduced using trichlorosilane. Additionally, (pentafluorophenyl)diphenylphosphine engages in two-stage cycloaddition reactions with nitrilimines, such as Housgen 1,3-dipoles, along with bis(pentafluorophenyl)(phenyl)phosphine, to produce fluorophosphoranes. These reactions demonstrate its precision in forming stable structures, highlighting its pivotal role in advanced chemical synthesis.

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