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Pentaammine(trifluoromethanesulfonato)osmium(III) triflate

Catalog Number
ACM83781300
Product Name
Pentaammine(trifluoromethanesulfonato)osmium(III) triflate
Structure
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CAS
83781-30-0
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Synonyms
Pentaammine(triflato)osmium(III) triflate
IUPAC Name
Azane;osmium;trifluoromethanesulfonate
Molecular Weight
722.6
Molecular Formula
C3H15F9N5O9OsS3
Canonical SMILES
C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].N.N.N.N.N.[Os]
InChI
InChI=1S/3CHF3O3S.5H3N.Os/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);5*1H3;/p-3
InChI Key
KJOSOZBKYCOBQT-UHFFFAOYSA-K
Melting Point
276 °C
Purity
99%+
Appearance
Powder
Complexity
145
Covalently-Bonded Unit Count
9
Defined Atom Stereocenter Count
0
Exact Mass
723.9503
Formal Charge
-3
H-Bond Acceptor
23
H-Bond Donor
5
Heavy Atom Count
30
Monoisotopic Mass
723.9503
Rotatable Bond Count
0
Topological Polar Surface Area
202 Ų
Application
Pentaammine(trifluoromethanesulfonato)osmium(III) triflate is designed to facilitate the dearomatization of anilines and enhance the stereoselective synthesis of cyclohexanediones through osmium(II)-promoted Michael additions to phenols. Additionally, it serves as a precursor for synthesizing Fischer carbyne complexes.
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