- Home
- Products
- Precious Metal Catalyst
- Palladium(II) acetate
Palladium(II) acetate
Catalog Number
ACM3375313
Product Name
Palladium(II) acetate
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/3375-31-3.gif)
CAS
3375-31-3
Synonyms
Aceticacid,palladium(2+)salt
IUPAC Name
Palladium(2+);diacetate
Molecular Weight
224.51
Molecular Formula
C12H18O12Pd3
Canonical SMILES
CC(=O)[O-].CC(=O)[O-].[Pd+2]
InChI
InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;+2/p-2
InChI Key
YJVFFLUZDVXJQI-UHFFFAOYSA-L
Melting Point
205 °C
Purity
95%+
Solubility
Insoluble in water
Appearance
Reddish-brown solid
Storage
Store below +30 °C
Color Form
powder
Complexity
25.5
Covalently-Bonded Unit Count
3
Defined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
EC Number
222-164-4/243-333-9
Empirical Formula
[Pd(OAc)2]3
Exact Mass
223.93009
H-Bond Acceptor
4
H-Bond Donor
0
Heavy Atom Count
9
Metal Content
47
Monoisotopic Mass
223.93009
Physical State
Solid
Rotatable Bond Count
223.93009
Topological Polar Surface Area
80.3 Ų
Undefined Atom Stereocenter Count
0
Undefined Bond Stereocenter Count
0
UNII
0
Application
Palladium(II) acetate, appearing as brown needles, serves as a highly versatile catalyst in various chemical reactions. Primarily soluble in benzene and toluene while insoluble in ether and alcohol, this compound is best stored in the dark and refrigerated to maintain its efficacy. Its primary use is in facilitating Suzuki-Miyaura cross-coupling and intramolecular coupling reactions, and it is essential in the chemoselective reduction of nitroarenes. Featuring a trimeric structure with D3h symmetry, each palladium atom is intricately linked via double acetate bridges, which enhances its function as a homogeneous oxidation catalyst. This unique arrangement aids in the activation of alkenic and aromatic compounds for oxidative nucleophilic reactions. Additionally, when microencapsulated in polyurea, palladium(II) acetate becomes a versatile heterogeneous catalyst useful for phosphine-free reactions. It plays a crucial role in the Heck coupling reaction, enabling efficient arylation of olefins and acting as a catalyst for C-H activation processes. Moreover, it functions as a precatalyst in the enantioselective decarboxylative protonation of allyl β-ketoesters, highlighting its extensive applicability in complex organic synthesis.
January 7, 2025
Reliable Catalyst for Cross-Coupling and C-H Activation
Palladium(II) acetate from Alfa Chemistry enhanced our Suzuki-Miyaura and Heck reactions. Its solubility in benzene and trimeric crystal structure make it effective and consistent for our aromatic compound activations. Efficient and versatile!
- CAS
- Size
- Purity
- Price
- Quantity
- Order
- 3375-31-3
- -
- 95%+
- -
-
- +
-
Online Inquiry
※ Please kindly note that our products are for research use only.
