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[P,P'-1,3-Bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium(0), 98%

Catalog Number
ACM123333459-1
Product Name
[P,P'-1,3-Bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium(0), 98%
Structure
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CAS
123333-45-9
  • Product Overview
  • Usage
Synonyms
BIS([3-(DIISOPROPYLPHOSPHANYL)PROPYL]DIISOPROPYLPHOSPHANE) PALLADIUM; MFCD06658138; [P,P'-1,3-bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium(0); [p,p-1,3-bis(di-i-propylphosphino)propane][p-1,3-bis(di-i-propylphosphino)propane]palladium(0); [P,P'-1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE][P-1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE]PALLADIUM (0);
IUPAC Name
3-di(propan-2-yl)phosphanylpropyl-di(propan-2-yl)phosphane;palladium;
Molecular Weight
659.189g/mol
Molecular Formula
C30H68P4Pd;
Canonical SMILES
CC(C)P(CCCP(C(C)C)C(C)C)C(C)C.CC(C)P(CCCP(C(C)C)C(C)C)C(C)C.[Pd];
InChI
InChI=1S/2C15H34P2.Pd/c2*1-12(2)16(13(3)4)10-9-11-17(14(5)6)15(7)8;/h2*12-15H,9-11H2,1-8H3;;
InChI Key
OYTRFAKJOIUDDD-UHFFFAOYSA-N;
Complexity
149
Covalently-Bonded Unit Count
3
Exact Mass
658.331g/mol
Heavy Atom Count
35
Monoisotopic Mass
658.331g/mol
Rotatable Bond Count
16
Topological Polar Surface Area
0A^2
Application
The product, [P,P'-1,3-Bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium(0), 98%, serves as a versatile catalyst with multiple applications. It is used for the cross-methylation of aryl chlorides, utilizing stabilized dimethylaluminum or dimethylgallium reagents to facilitate this transformation. Additionally, it acts as an efficient catalyst in the carbonylation of aryl chlorides, helping to introduce carbonyl groups effectively. Moreover, the product is employed in base-free olefin arylation, providing a robust method for forming carbon-carbon bonds without the need for additional bases.
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