CAS 166330-10-5 (Oxybis(2,1-phenylene))bis(diphenylphosphine)

IUPAC Name

[2-(2-diphenylphosphanylphenoxy)phenyl]-diphenylphosphane;

Molecular Weight

538.567g/mol

Molecular Formula

C36H28OP2;

InChI

InChI=1S/C36H28OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H;

InChI Key

RYXZOQOZERSHHQ-UHFFFAOYSA-N;

Complexity

594

Covalently-Bonded Unit Count

Exact Mass

538.162g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

538.162g/mol

Rotatable Bond Count

Topological Polar Surface Area

9.2A^2

MSDS

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COA

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Spec Sheet

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Application

Useful as a ligand in the Pd-catalyzed formation of diaryl amines.

Has been recently applied to the C3 benzylation of indoles.

Has been recently applied to the monoallylation of ammonia.

Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.

Ligand used in carbonylation of aryl iodides.

Ligand used in the direct C-H arylation of benzothiodiazoles.

Ligand used in stereo-retentive azacyclization of propargylic carbonates.

Ligand used in palladium catalyzed benzyne trimerization.