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Oxotrichloro[bis(diphenylphosphino)methane]rhenium(V)

Catalog Number
ACM60260175
Product Name
Oxotrichloro[bis(diphenylphosphino)methane]rhenium(V)
CAS
60260-17-5
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Synonyms
Trichloro[methylenebis[diphenylphosphine]-P,P']oxorhenium
IUPAC Name
fac-{ReOCl3(dppm-P,P)}
Molecular Weight
692.96
Molecular Formula
C25H22Cl3OP2Re
Purity
96%
Exact Mass
691.97700
Application
Oxotrichloro[bis(diphenylphosphino)methane]rhenium(V) serves as a versatile catalyst designed to facilitate a range of chemical reactions with efficiency and precision. Its applications include the epoxidation of olefins using hydrogen peroxide in conjunction with activated bicarbonate, ensuring effective oxidant utilization. Additionally, this catalyst is instrumental in the efficient reduction of aromatic sulfoxides. It also plays a crucial role in the regioselective coupling of propargyl alcohols with sulfonamides and carbamates, providing specificity and control in complex syntheses. Furthermore, Oxotrichloro[bis(diphenylphosphino)methane]rhenium(V) supports cycloisomerization reactions, highlighting its multifaceted utility in advancing chemical transformations.
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