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N,N'-Bis(salicylidene)ethylenediaminocobalt(II)

Catalog Number
ACM14167181-3
Product Name
N,N'-Bis(salicylidene)ethylenediaminocobalt(II)
Structure
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CAS
14167-18-1
  • Product Overview
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Synonyms
N2O9115YTK; Salicylaldehyde ethylenediimine cobalt; Cobalt, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-, (SP-4-2)-; SCHEMBL510827; cobalt(2+); AI3-30876; (Ethylenebis(nitrilomethylidyne)-2,2'-diphenolato)cobalt(II); cobalt(2+) 2-{[(2-{[(2-oxidophenyl)methylidene]amino}ethyl)imino]methyl}benzenolate; N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II); SALCOMINE;
IUPAC Name
cobalt(2+);2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate;
Molecular Weight
325.233g/mol
Molecular Formula
C16H14CoN2O2;
Canonical SMILES
C1=CC=C(C(=C1)C=NCCN=CC2=CC=CC=C2[O-])[O-].[Co+2];
InChI
InChI=1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2;
InChI Key
NPAQSKHBTMUERN-UHFFFAOYSA-L;
Solubility
Soluble in benzene, chloroform, and pyridine;
Color Form
Red crystals from DMF;Dark brown powder;
Complexity
298
Covalently-Bonded Unit Count
2
Decomposition
When heated to decomposition it emits toxic fumes of /nitrous oxide/.;
EC Number
238-012-5
Exact Mass
325.039g/mol
H-Bond Acceptor
4
Heavy Atom Count
21
Monoisotopic Mass
325.039g/mol
Other Experimental
Ionization energy (IE): 7.52 eV;No rapid reaction with air. No rapid reaction with water.;
Rotatable Bond Count
5
Stability
Stable under recommended storage conditions.;
Topological Polar Surface Area
70.8A^2
UNII
N2O9115YTK
Application
N,N'-Bis(salicylidene)ethylenediaminocobalt(II), a black crystalline powder, serves as a versatile catalyst primarily in oxidation reactions. It functions by facilitating the oxidation of 2,6-disubstituted phenols through its interaction with dioxygen. As a solid complex formed between cobalt(II) ions and the condensation product of salicylaldehyde and ethylenediamine, known as a Schiff's base, its basic properties are neutralized upon complexation with cobalt. This transformation enables it to act as an effective oxygen carrier, thereby enhancing the rate of oxidation processes, such as converting amines to nitro compounds via peroxides or hydroperoxides. Additionally, it has been studied for its potential to inhibit human cytomegalovirus proteinase activity and finds use as a redox catalyst in metal complex dyes.
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