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Molybdenum(VI) tetrachloride oxide

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Catalog Number
ACM13814750-1
Product Name
Molybdenum(VI) tetrachloride oxide
Structure
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CAS
13814-75-0
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IUPAC Name
oxomolybdenum;tetrahydrochloride;
Molecular Weight
257.781g/mol
Molecular Formula
Cl4H4MoO;
Canonical SMILES
O=[Mo].Cl.Cl.Cl.Cl;
InChI
InChI=1S/4ClH.Mo.O/h4*1H;;;
InChI Key
SFPKXFFNQYDGAH-UHFFFAOYSA-N;
Complexity
7.5
Covalently-Bonded Unit Count
5
Exact Mass
259.804g/mol
H-Bond Acceptor
1
H-Bond Donor
4
Heavy Atom Count
6
Monoisotopic Mass
257.807g/mol
Topological Polar Surface Area
17.1A^2
Application
Molybdenum(VI) tetrachloride oxide is a green powder that is sensitive to moisture and volatile at ordinary temperatures. It serves multiple purposes in chemical applications. Primarily, it is utilized to prepare a binary metal catalyst (MoOCl4-n-BuLi) which is effective in the living polymerization of various acetylenes. Additionally, it acts as an oxidant in the aromatization of Hantzsch-1,4-dihydropyridines, and serves as a molybdenum precursor in the creation of nafion-Mo composite materials, which are used as catalysts in synthesizing nitrones through the reaction of primary amines with aldehydes.
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