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(4-Methylphenyl)diphenyl phosphine

Catalog Number
ACM1031932-2
Product Name
(4-Methylphenyl)diphenyl phosphine
Structure
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CAS
1031-93-2
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Synonyms
ZINC59904947; RT-004964; Diphenyl(p-tolyl)phosphine, 96%; ST24030390; Phosphine, (4-methylphenyl)diphenyl-; SC11156; AC1L2EDT; AKOS015914280; (4-methylphenyl)diphenylphosphane; PubChem6424;
IUPAC Name
(4-methylphenyl)-diphenylphosphane;
Molecular Weight
276.319g/mol
Molecular Formula
C19H17P;
Canonical SMILES
CC1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3;
InChI
InChI=1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3;
InChI Key
QJIMTLTYXBDJFC-UHFFFAOYSA-N;
Complexity
250
Covalently-Bonded Unit Count
1
EC Number
213-848-3
Exact Mass
276.107g/mol
Heavy Atom Count
20
Monoisotopic Mass
276.107g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
0A^2
Application
(4-Methylphenyl)diphenyl phosphine is a versatile compound that appears as a white to light yellow crystal powder. Its primary purpose is to serve as a reactant in various chemical processes. It is used in three-component cyclization reactions and plays a crucial role in investigating coordination abilities through palladium pincer complexes. Additionally, it is involved in chelation-assisted hydroacylation of olefins with primary alcohols. This compound is also integral to the synthesis of trinuclear ruthenium carbonyl triarylphosphine cluster complexes. Beyond these applications, it is utilized in the development of leishmanicidal leads that target mitochondria by inhibiting the respiratory complex, and is a precursor for creating InP nanofibers and metal phosphide nanostructures. Furthermore, it is used in generating peroxyl radical cations through pulse radiolysis one-electron oxidations, as referenced in The Journal of Organic Chemistry, 52, p. 748, 1987.
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