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Methyl(triphenylphosphine)gold(I)

Catalog Number
ACM23108727
Product Name
Methyl(triphenylphosphine)gold(I)
Structure
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CAS
23108-72-7
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Synonyms
Carbanide;gold(1+);triphenylphosphane
IUPAC Name
carbanide;gold(1+);triphenylphosphane;
Molecular Weight
474.3
Molecular Formula
C19H18AuP
Canonical SMILES
[CH3-].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Au+]
InChI
InChI=1S/C18H15P.CH3.Au/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H3;/q;-1;+1
InChI Key
AIJHVWFIEVTCNT-UHFFFAOYSA-N
Melting Point
150 °C
Purity
99%
Appearance
Crystal
Storage
2-8°C
Complexity
204
Covalently-Bonded Unit Count
3
Exact Mass
474.081183
H-Bond Acceptor
1
Heavy Atom Count
21
Monoisotopic Mass
474.081183
Rotatable Bond Count
3
Topological Polar Surface Area
0 Ų
Application
Methyl(triphenylphosphine)gold(I) serves as a versatile and highly efficient catalyst designed for various organic transformations. It facilitates the addition of water to alkynes, thereby promoting intermolecular hydroamination processes with remarkable efficiency. Additionally, it plays a crucial role in relay catalysis when combined with a Bronsted acid, enabling the synthesis of complex benzoxasiloles. Its catalytic prowess extends to promoting the intermolecular hydroarylation of alkenes with indoles, showcasing its broad applicability and effectiveness in modern synthetic chemistry.
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