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Manganese(II) chloride monohydrate

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Catalog Number

ACM64333013

Product Name

Structure

CAS

64333-01-3

Product Overview
Usage

Synonyms

Manganese dichloride monohydrate

IUPAC Name

dichloromanganese;hydrate

Molecular Weight

143.86

Molecular Formula

Cl2Mn·H2O

Canonical SMILES

O.Cl[Mn]Cl

InChI Key

BXRRQHBNBXJZBQ-UHFFFAOYSA-L

Melting Point

122ºC(lit.)

Purity

96%

Density

1.913 g/mL at 25ºC(lit.)

Storage

room temperature

EC Number

613-575-3

Exact Mass

142.88600

H-Bond Acceptor

H-Bond Donor

Application

Manganese(II) chloride monohydrate serves as a versatile compound with numerous applications in various chemical processes. It is primarily used as a starting material for the preparation of organomanganese chloride reagents. When combined with RLi or RMgX, it effectively catalyzes the reduction of vinyl and aryl halides, facilitates the stereoselective coupling of vinyl iodides, and supports the alkylation of enol triflates. Additionally, it plays a crucial role in Mn-Cu-catalyzed conjugate addition of RMgX to enones and Mn-catalyzed acylation of RMgX by acyl chlorides. Furthermore, in combination with NaBH4, it acts as a diastereoselective reducing agent and is employed as a starting material for the regio- and stereoselective preparation of manganese enolates.

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CAS
Size
Purity
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64333-01-3
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96%
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