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Manganese(II) chloride hydrate
PRICE INQUIRYCatalog Number
ACM73913061-1
Product Name
Manganese(II) chloride hydrate
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/73913-06-1.gif)
CAS
73913-06-1
Synonyms
MANGANESE(II) CHLORIDE HYDRATE99.999%;Manganese(II) chloride hydrate 99.999% trace metals basis
IUPAC Name
manganese(2+);dichloride;hydrate
Molecular Weight
143.86g/mol
Molecular Formula
Cl2H2MnO
Canonical SMILES
O.[Cl-].[Cl-].[Mn+2]
InChI
InChI=1S/2ClH.Mn.H₂O/h2*1H;;1H2/q;;+2;/p-2
InChI Key
BXRRQHBNBXJZBQ-UHFFFAOYSA-L
Storage
2-8°C
Complexity
0
Covalently-Bonded Unit Count
4
EC Number
613-575-3
Exact Mass
142.886313g/mol
Formal Charge
0
H-Bond Acceptor
3
H-Bond Donor
1
Heavy Atom Count
4
Monoisotopic Mass
142.886313g/mol
Rotatable Bond Count
0
UNII
9DXE21J14O
Application
Manganese(II) chloride hydrate serves as a versatile starting material for a variety of chemical processes, particularly in the preparation of organomanganese chloride reagents. It plays a critical role when combined with organolithium (RLi) or organomagnesium (RMgX) compounds, efficiently catalyzing the reduction of vinyl and aryl halides, facilitating the stereoselective coupling of vinyl iodides, and promoting the alkylation of enol triflates. Additionally, it is employed in Mn-Cu-catalyzed conjugate additions of RMgX to enones and Mn-catalyzed acylation of RMgX by acyl chlorides. When used with sodium borohydride (NaBH4), it acts as a diastereoselective reducing agent. Furthermore, manganese(II) chloride hydrate is instrumental in the regio- and stereoselective preparation of manganese enolates, making it a crucial component in advanced organic synthesis.
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