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Manganese(II) chloride bis(lithium chloride) complex solution

Catalog Number
ACM57384244-1
Product Name
Manganese(II) chloride bis(lithium chloride) complex solution
CAS
57384-24-4
  • Product Overview
  • Usage
Synonyms
Lithium manganese chloride, AGN-PC-00GJHY, Lithium chloromanganate(II), dilithium;tetrachloromanganese(2-), Lithium tetrachloromanganate(II) solution, Manganese(II) chloride bis(lithium chloride) complex solution, 57384-24-4
IUPAC Name
dilithium;tetrachloromanganese(2-)
Molecular Weight
210.63
Molecular Formula
Cl4Li2Mn
Canonical SMILES
[Li+].[Li+].Cl[Mn-2](Cl)(Cl)Cl
InChI
InChI=1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4;
InChI Key
VJOUQNFWQPCDPE-UHFFFAOYSA-J
Boiling Point
67ºC
Flash Point
-2 °F
Purity
96%
Density
0.976 g/mL at 25ºC
Complexity
19.1
Covalently-Bonded Unit Count
3
Exact Mass
208.84500
H-Bond Acceptor
1
H-Bond Donor
0
Heavy Atom Count
7
Monoisotopic Mass
208.845g/mol
Topological Polar Surface Area
0A^2
Application
The Manganese(II) chloride bis(lithium chloride) complex solution serves as a versatile reagent, primarily used as a catalyst for the homocoupling of Grignard reagents with atmospheric oxygen acting as an oxidant. In addition, it plays a crucial role in transmetalation reactions and facilitates nickel-imidazolium carbene-catalyzed coupling reactions. Furthermore, it is an essential reagent in the preparation of Rieke manganese, showcasing its broad applicability in various chemical synthesis processes.
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