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Lanthanum(III) trifluoromethanesulfonate

Catalog Number
ACM52093262
Product Name
Lanthanum(III) trifluoromethanesulfonate
Structure
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CAS
52093-26-2
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  • Usage
Synonyms
Lanthanum(III) triflate
IUPAC Name
lanthanum(3+);trifluoromethanesulfonate;
Molecular Weight
586.1
Molecular Formula
C3F9LaO9S3
Canonical SMILES
C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[La+3]
InChI
InChI=1S/3CHF3O3S.La/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;+3/p-3
InChI Key
WGJJZRVGLPOKQT-UHFFFAOYSA-K
Purity
98%
Appearance
Powder
Storage
Refrigerator
Complexity
145
Covalently-Bonded Unit Count
4
Defined Atom Stereocenter Count
0
Exact Mass
585.762436
H-Bond Acceptor
18
Heavy Atom Count
25
Monoisotopic Mass
585.762436
Rotatable Bond Count
0
Topological Polar Surface Area
197 Ų
Application
Lanthanum(III) trifluoromethanesulfonate is a versatile, water-tolerant Lewis acid that serves as an effective catalyst in a variety of chemical reactions. This white to light beige crystalline powder is employed in the Aldol reaction, facilitating the reaction between silyl enol ethers and aldehydes. Additionally, it acts as a reliable catalyst for the Baylis-Hillman reaction, as well as promoting Michael additions to methyl vinyl ketone in an aqueous environment, showcasing its efficacy in organic synthesis.
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