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Hydridotetrakis(triphenylphosphine)rhodium(I)

Catalog Number
ACM18284361
Product Name
Hydridotetrakis(triphenylphosphine)rhodium(I)
Structure
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CAS
18284-36-1
  • Product Overview
  • Usage
Synonyms
Rhodium;triphenylphosphane
IUPAC Name
rhodium;triphenylphosphane;
Molecular Weight
1152
Molecular Formula
C72H60P4Rh
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]
InChI
InChI=1S/4C18H15P.Rh/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI Key
IGTVAJJAPJKARK-UHFFFAOYSA-N
Melting Point
140-146 °C
Purity
99%
Appearance
Powder
Complexity
202
Covalently-Bonded Unit Count
5
Exact Mass
1151.27004
Heavy Atom Count
77
Monoisotopic Mass
1151.27004
Rotatable Bond Count
12
Topological Polar Surface Area
0 Ų
Application
Hydridotetrakis(triphenylphosphine)rhodium(I) is a yellow powder that serves as a catalyst in a variety of chemical reactions. This inorganic compound is particularly utilized as a starting material in the formation of a rhodium/phosphine complex, which plays a crucial role in synthesizing diarylsulfides from aryl fluorides and sulfur or organopolysulfides.
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