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Hexarhodium(0) hexadecacarbonyl

Hexarhodium(0) hexadecacarbonyl

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Catalog Number

ACM28407514-2

Product Name

Structure

CAS

28407-51-4

Product Overview
Usage

Synonyms

Rhodium, tetra-m3-carbonyldodecacarbonylhexa-,octahedro; Hexarhodium hexadecacarbonyl; SZQABOJVTZVBHE-UHFFFAOYSA-N; HEXARHODIUMHEXADECACARBONYL; Rhodium(0) carbonyl; HEXADECACARBONYLHEXARHODIUM; RL02967; Hexarhodium(0) hexadecacarbonyl, Rh 57-60 % (approx.);

IUPAC Name

carbon monoxide;rhodium;

Molecular Weight

1065.593g/mol

Molecular Formula

Rh6(CO)16;C16O16Rh6;

Canonical SMILES

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Rh].[Rh].[Rh].[Rh].[Rh].[Rh];

InChI

InChI=1S/16CO.6Rh/c16*1-2;;;;;;;

InChI Key

SZQABOJVTZVBHE-UHFFFAOYSA-N;

Complexity

Covalently-Bonded Unit Count

EC Number

249-009-3

Exact Mass

1065.352g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

1065.352g/mol

Topological Polar Surface Area

16A^2

Application

Hexarhodium(0) hexadecacarbonyl serves a pivotal role as a versatile catalyst due to its unique cluster structure and black crystal form. It is extensively utilized in the hydrogenation of alkenes and the hydroformylation of alkenes, making it invaluable to various industrial processes. Additionally, this compound functions as a reducing agent for aldehydes, ketones, and nitro groups, and it catalyzes carbenoid reactions of diazo compounds.

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