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Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L)

Catalog Number
ACM15489277-4
Product Name
Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L)
Structure
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CAS
15489-27-7
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Synonyms
DilithiumTetrachlorocopper(II)(ca.2.5%inTetrahydrofuran,ca.0.1mol/L); Lithium tetrachlorocuprate, 0.1M in THF; KS-000017QU; Dilithium tetrachlorocuprate, 0.1M solution in THF, AcroSeal(R); AKOS030228377;
IUPAC Name
dilithium;tetrachlorocopper(2-);
Molecular Weight
219.226g/mol
Molecular Formula
Cl4CuLi2;
Canonical SMILES
[Li+].[Li+].Cl[Cu-2](Cl)(Cl)Cl;
InChI
InChI=1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4;
InChI Key
HCJWWBBBSCXJMS-UHFFFAOYSA-J;
Storage
Flammables area
Complexity
19.1
Covalently-Bonded Unit Count
3
Exact Mass
218.834g/mol
H-Bond Acceptor
1
Heavy Atom Count
7
Monoisotopic Mass
216.837g/mol
Topological Polar Surface Area
0A^2
Application
Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L) is a versatile clear orange to brown-red solution utilized in various chemical reactions to enhance efficiency and selectivity. This organic-soluble copper catalyst is particularly effective in coupling alkyl halides with alkyl Grignard reagents, thereby facilitating complex molecule synthesis. Additionally, it plays a crucial role in the halogenation of pyrimidine nucleosides. The catalyst is employed in catalytic quantities to improve the displacement efficiency of halides and allylic acetates when used with Grignard reagents. Moreover, in stoichiometric amounts, it is instrumental in opening epoxides and aziridines, thus broadening its utility in synthetic organic chemistry.
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