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2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide

Catalog Number
ACM934506102-2
Product Name
2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide
Structure
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CAS
934506-10-2
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Synonyms
XPhos AuNTf2
IUPAC Name
bis(trifluoromethylsulfonyl)azanide;dicyclohexyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;gold(1+)
Molecular Weight
953.83
Molecular Formula
C35H49AuF6NO4PS2
Canonical SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C)C.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Au+]
InChI Key
GMVGZINKTXAKDT-UHFFFAOYSA-N
Purity
96%
Appearance
white to off-white powder
Exact Mass
953.24100
H-Bond Acceptor
11
H-Bond Donor
0
MDL Number
MFCD10567016
Symbol
GHS07
Application
2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide serves as a cutting-edge catalyst designed to enhance various chemical reactions, most notably the isomerization of allenyl carbinol esters. Additionally, it effectively facilitates hydroxy- and methoxycyclization processes, as well as the cycloisomerization of diynes, making it an invaluable tool for researchers and chemists aiming to streamline synthetic pathways and improve efficiency in complex organic transformations.
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