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Dichlorodi-μ-chlorobis[(1,2,3,6,7,8-η-2,7-dimethyl-2,6-octadiene-1,8-diyl]diruthenium(IV)

Dichlorodi-μ-chlorobis[(1,2,3,6,7,8-η-2,7-dimethyl-2,6-octadiene-1,8-diyl]diruthenium(IV)

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Catalog Number

ACM34801973-2

Product Name

Structure

CAS

34801-97-3

Product Overview
Usage

Synonyms

Tetrachlorobis(2,7-dimethyl-2,6-octadienylene)diruthenium

Molecular Weight

616.42

Molecular Formula

C₂₀H₃₂Cl₄Ru₂

Melting Point

193-202 °C (dec.)

Purity

0.98

Appearance

red to purple powder

Symbol

GHS07

Application

Dichlorodi-μ-chlorobis[(1,2,3,6,7,8-η-2,7-dimethyl-2,6-octadiene-1,8-diyl]diruthenium(IV) serves multiple catalytic purposes in advanced chemical synthesis. It is employed for the selective isomerization of estragole to transanethole, and facilitates the regioselective alkylation of indoles with terminal alkynes. Additionally, it is effective in promoting diyne polycyclotrimerization and the deprotection of N-allylic amines. This compound also plays a crucial role in ring-opening metathesis polymerization of norbornene, as well as the polymerization of cycloalkenes and norbornene. Furthermore, it is a versatile starting material for synthesizing cyclic and acyclic bis(η5-dienyl)ruthenium (II) compounds, underscoring its importance in the preparation of complex molecular structures.

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CAS
Size
Purity
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34801-97-3
-
0.98
-
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