Molecular Weight
701.91
Molecular Formula
C36H30Cl2P2Pd
Purity
Metal purity 99.95
Appearance
yellow
Color Form
powder
Empirical Formula
[Pd(PPh3)2Cl2]
Metal Content
15
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- Dichlorobis(triphenylphosphine)palladium(II)
Dichlorobis(triphenylphosphine)palladium(II)
Catalog Number
ACM13965032-4
Product Name
Dichlorobis(triphenylphosphine)palladium(II)
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/13965-03-2.gif)
CAS
13965-03-2
Application
Dichlorobis(triphenylphosphine)palladium(II) serves as a versatile organometallic complex known for its pivotal role in palladium-catalyzed coupling reactions, including various cross-coupling reactions such as Negishi, Suzuki, Sonogashira, and Heck reactions. As a yellow solid, it exhibits poor water solubility but can dissolve in organic solvents like toluene and benzene, with slight solubility in acetone and chloroform. This compound, adopting a square planar geometry, acts as a valuable catalyst and precatalyst across multiple reactions: it facilitates carbonylative cyclization of malonate derivatives, double allylation of activated olefins, preparation of 3-arylidene- or 3-alkenylidene tetrahydrofurans, and homocoupling of terminal alkynes. Additionally, it contributes to the cross-coupling of alkynylsilanols with aryl halides, supports direct Pd-catalyzed alkynylation of N-fused heterocycles, and assists in tandem Heck reaction/C-H functionalization as well as in the direct arylation of tautomerizable heterocycles.
January 2, 2025
Essential for Efficient Cross-Coupling Reactions!
Dichlorobis(triphenylphosphine)palladium(II) is pivotal in our lab's Suzuki couplings. It dissolves well in organic solvents, making it easy to use. A reliable choice for precise catalysis in complex reactions.
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