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Dichlorobis(2-(diisopropylphosphino)-ethylamine)ruthenium(II)

Catalog Number
ACM1092372901-2
Product Name
Dichlorobis(2-(diisopropylphosphino)-ethylamine)ruthenium(II)
Structure
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CAS
1092372-90-1
  • Product Overview
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Synonyms
MFCD07782005; RT-004898; SC10245; Dichlorobis[2-(di-i-propylphosphino)ethylamine]ruthenium (II); Dichlorobis(2-(diisopropylphosphino)-ethylamine)ruthenium(II), 97%; 1092372-90-1;
IUPAC Name
dichlororuthenium;2-di(propan-2-yl)phosphanylethanamine;
Molecular Weight
494.428g/mol
Molecular Formula
C16H40Cl2N2P2Ru;
Canonical SMILES
CC(C)P(CCN)C(C)C.CC(C)P(CCN)C(C)C.Cl[Ru]Cl;
InChI
InChI=1S/2C8H20NP.2ClH.Ru/c2*1-7(2)10(6-5-9)8(3)4;;;/h2*7-8H,5-6,9H2,1-4H3;2*1H;/q;;;;+2/p-2;
InChI Key
HINVYXXIKGEKJI-UHFFFAOYSA-L;
Complexity
76.1
Covalently-Bonded Unit Count
3
Exact Mass
494.109g/mol
H-Bond Acceptor
2
H-Bond Donor
2
Heavy Atom Count
23
Monoisotopic Mass
494.109g/mol
Rotatable Bond Count
8
Topological Polar Surface Area
52A^2
Application
Dichlorobis(2-(diisopropylphosphino)-ethylamine)ruthenium(II) serves as an exceptionally active catalyst specifically designed for the hydrogenation of ketones and imines, operating effectively under mild conditions. Its unique capability lies in its selectivity, as it preferentially targets the hydrogenation of carbon-oxygen (C=O) bonds while leaving carbon-carbon (C=C) bonds largely unaffected.
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