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Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 90%

Catalog Number
ACM212210872
Product Name
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 90%
Structure
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 90%
CAS
212210-87-2
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Synonyms
Dichloro[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)1,1 inverted exclamation marka-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II); RUCL2((S)-BINAP)(S,S-DPEN); MFCD02684566; 1-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II; Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine] ruthenium(II), 95%; DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLELENEDIAMINE]RUTHENIUM(II); Dichloro[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine] ruthenium(II); 329736-05-2; Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), 95%;
IUPAC Name
dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;
Molecular Weight
1006.954g/mol
Molecular Formula
C58H48Cl2N2P2Ru;
InChI
InChI=1S/C44H32P2.C14H16N2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h1-32H;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.0.../s1;
InChI Key
PZTVCDSGEXHVBL-LISIALKWSA-L;
Complexity
971
Covalently-Bonded Unit Count
3
Defined Atom Stereocenter Count
2
Exact Mass
1006.171g/mol
H-Bond Acceptor
2
H-Bond Donor
2
Heavy Atom Count
65
Monoisotopic Mass
1006.171g/mol
Rotatable Bond Count
10
Topological Polar Surface Area
52A^2
Application
The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1,2-diamine ligand. The catalysts are used in the highly-efficient, enantio and diastereoselective hydrogenation of simple ketones, usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure.
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