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Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II), 97%

Catalog Number
ACM444910172-1
Product Name
Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II), 97%
Structure
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CAS
444910-17-2
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Synonyms
FT-0683884; 2-(6-Methyl-pyridin-2-yl)-ethylamine; ZINC4202821; X7037; TRA0015781; 2-(2'-Aminoethyl)-6-methylpyridine; [2-(6-METHYLPYRIDIN-2-YL)ETHYL]AMINE; ANW-72514; AB1009078; CTK4E1305;
IUPAC Name
2-(6-methylpyridin-2-yl)ethanamine;
Molecular Weight
136.198g/mol
Molecular Formula
C8H12N2;
Canonical SMILES
CC1=NC(=CC=C1)CCN;
InChI
InChI=1S/C8H12N2/c1-7-3-2-4-8(10-7)5-6-9/h2-4H,5-6,9H2,1H3;
InChI Key
CDTHKXWPZVCHBX-UHFFFAOYSA-N;
Storage
2-8°C
Complexity
93.3
Covalently-Bonded Unit Count
1
Exact Mass
136.1g/mol
H-Bond Acceptor
2
H-Bond Donor
1
Heavy Atom Count
10
Monoisotopic Mass
136.1g/mol
Rotatable Bond Count
2
Topological Polar Surface Area
38.9A^2
Application
Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II), 97%, serves as a versatile catalyst with multiple applications in organic synthesis. Its primary purpose is to facilitate various chemical reactions, such as the intramolecular direct arylation reaction involving aryl chlorides and aryl amination. Additionally, it is utilized in the aerobic oxidative kinetic resolution of secondary alcohols, showcasing its efficiency in enantioselective processes. The catalyst also demonstrates high activity in the Mizoroki-Heck reaction, a key transformation in the formation of carbon-carbon bonds. Furthermore, it plays a crucial role in the hydrodehalogenation of polychlorinated biphenyls, offering an effective approach to dechlorination. As an orange solid, this compound is indispensable in both research and industrial settings, contributing to advancements in chemical synthesis with its broad catalytic capabilities.
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