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Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)

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Catalog Number

ACM205319068-3

Product Name

Structure

CAS

205319-06-8

Product Overview
Usage

Synonyms

Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II)

Molecular Weight

715.88

Molecular Formula

C36H28Cl2OP2Pd

Canonical SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3OC4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6.Cl[Pd]Cl

InChI

InChI=1S/C36H28OP2.2ClH.Pd/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32;/h1-28H;2*1H;/q;+2/p-2

InChI Key

VYOUBMJFTDMKRR-UHFFFAOYSA-L

Purity

99%

Appearance

Light yellow powder

Color Form

powder

Complexity

597

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Empirical Formula

[Pd(DPEphos)Cl2]

Exact Mass

714.00273

Heavy Atom Count

Metal Content

Monoisotopic Mass

714.00273

Rotatable Bond Count

Topological Polar Surface Area

9.2 Å²

Application

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II), a light yellow powder, serves as a catalyst in the synthesis of conjugated Z,E dienes with high stereoselectivity through the cross-coupling reaction of 2-brom-1,3-dienes. Additionally, it facilitates stereoretentive Kumada-Corriu couplings of alkenyl halides at room temperature, enabling highly selective reactions in Negishi-Plus couplings of unbiased alkenyl halides.

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CAS
Size
Purity
Price
Quantity
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205319-06-8
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99%
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