CAS 3240-34-4 (Diacetoxyiodo)benzene - Catalysts / Alfa Chemistry

Synonyms

CS-W011998; ST24032066; Phenyliodine diacetate; Iodine, bis(acetato-O)phenyl- (9CI); PIDA; bis(acetyloxy)(phenyl)-lambda~3~-iodane; Phenyliodine(III) diacetate; (acetyloxy)(phenyl)- -iodanyl acetate; Phenyliodo diacetate; 240I344;

IUPAC Name

[acetyloxy(phenyl)-λ3-iodanyl] acetate;

Molecular Weight

322.098g/mol

Molecular Formula

C10H11IO4;

Canonical SMILES

CC(=O)OI(C1=CC=CC=C1)OC(=O)C;

InChI

InChI=1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3;

InChI Key

ZBIKORITPGTTGI-UHFFFAOYSA-N;

Storage

-20°C

Complexity

220

Covalently-Bonded Unit Count

EC Number

221-808-1

Exact Mass

321.97g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

321.97g/mol

NSC Number

226375

Rotatable Bond Count

Topological Polar Surface Area

52.6A^2

Application

(Diacetoxyiodo)benzene, a white to light yellow crystalline powder, serves as a versatile hypervalent iodine reagent and oxidizing agent. It is primarily used in the oxidative decarboxylation of 2-aryl carboxylic acids to produce aldehydes, ketones, and nitriles when combined with a catalytic amount of sodium azide in acetonitrile. Beyond this chemical transformation, (Diacetoxyiodo)benzene has diverse applications in the medical and industrial fields. It is an essential component in the formulation of antiseptics, disinfectants, and pharmaceutical intermediates. Additionally, it plays a role in the production of polarizing films for liquid crystal display (LCD) technology, as well as in various human and animal nutrition products.

March 3, 2025

Versatile Oxidizing Agent for Research

Used (Diacetoxyiodo)benzene in oxidative decarboxylation of 2-aryl carboxylic acids. Efficiently transformed them into aldehydes in our lab, proving its reliability in producing ketones and nitriles too. A valuable reagent for various applications.