CAS 12354-84-6 Di( µ -chloro)dichlorobis(pentamethylcyclopentadienyl)diiridium(III)

Molecular Weight

796.70

Molecular Formula

C20H30Cl4Ir2

Purity

Metal purity 99.95

Appearance

red orange

Color Form

powder

Empirical Formula

[Ir(C5Me5)Cl2]2

Metal Content

Application

The product, Di(µ-chloro)dichlorobis(pentamethylcyclopentadienyl)diiridium(III), serves as a versatile precursor in catalyst development for various chemical reactions. It is instrumental in the asymmetric transfer hydrogenation of ketones, promoting greener synthesis processes for amines. Additionally, this compound supports iridium-catalyzed C-3 alkylation of oxindole utilizing alcohols and acts as a precursor to N-heterocyclic carbene catalysts effective in the hydrogenation and alkylation of amines and alcohols. It also aids in creating phosphine-free catalysts for the enantioselective hydrogenation of quinoline derivatives. Furthermore, it functions as a catalyst for oxidative C-H activation and a precursor to water oxidation catalysts, with enhancements focused on catalytic efficiency, making it a valuable component in sustainable chemistry.

March 12, 2025

Highly Effective Catalyst Precursor for Research

As a researcher, I found Di(µ-chloro)dichlorobis(pentamethylcyclopentadienyl)diiridium(III) indispensable for catalyst preparation. Its efficacy in asymmetric transfer hydrogenation and C-H activation greatly enhanced our project's outcomes. Highly recommend for scientific applications.