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1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate

1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate

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Catalog Number

ACM120967706-2

Product Name

Structure

CAS

120967-70-6

Product Overview
Usage

Synonyms

120967-70-6;CYCLOOCTADIENE(HYDROQUINONE)RHODIUM (I) TETRAFLUOROBORATE;1,5-CYCLOOCTADIENE(HYDROQUINONE)RHODIUM(I) TETRAFLUOROBORATE;MFCD09753039;SC10113;1,5-Cyclooctadiene(hydroquinone)rhodium(I)tetrafluoroborate;

IUPAC Name

benzene-1,4-diol;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate;

Molecular Weight

408.005g/mol

Molecular Formula

C14H18BF4O2Rh-;

Canonical SMILES

[B-](F)(F)(F)F.C1CC=CCCC=C1.C1=CC(=CC=C1O)O.[Rh];

InChI

InChI=1S/C8H12.C6H6O2.BF4.Rh/c1-2-4-6-8-7-5-3-1;7-5-1-2-6(8)4-3-5;2-1(3,4)5;/h1-2,7-8H,3-6H2;1-4,7-8H;;/q;;-1;/b2-1-,8-7-;;;;

InChI Key

AZTYAQCGFXPPHA-PHFPKPIQSA-N;

Complexity

147

Covalently-Bonded Unit Count

Defined Bond Stereocenter Count

Exact Mass

408.039g/mol

Formal Charge

-1

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

408.039g/mol

Topological Polar Surface Area

40.5A^2

Application

1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate serves as a phosphorous-free pre-catalyst designed for the efficient 1,4-conjugate addition of arylboronic acids to enones. This innovative compound facilitates a key reaction in organic synthesis, providing a more streamlined and effective approach to conjugate addition without the need for phosphorous-based components.

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