Cy-cBRIDP
Catalog Number
ACM1023330382-1
Product Name
Cy-cBRIDP
CAS
1023330-38-2
Synonyms
Dicyclohexyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; Cy-cBRIDP; 1-(Dicyclohexylphosphino)-2,2-Diphenyl-1-methylcyclopropane; Cy-cBRIDP, 97%; Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine Cy-BRIDP; Dicyclohexyl(1-methyl-2,2-diphenylcyclopropyl)phosphane; SCHEMBL377463; 2,2-DIPHENYL-1-(DICYCLOHEXYLPHOSPHINO)-1-METHYLCYCLOPROPANE;
IUPAC Name
dicyclohexyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;
Molecular Weight
404.578g/mol
Molecular Formula
C28H37P;
Canonical SMILES
CC1(CC1(C2=CC=CC=C2)C3=CC=CC=C3)P(C4CCCCC4)C5CCCCC5;
InChI
InChI=1S/C28H37P/c1-27(29(25-18-10-4-11-19-25)26-20-12-5-13-21-26)22-28(27,23-14-6-2-7-15-23)24-16-8-3-9-17-24/h2-3,6-9,14-17,25-26H,4-5,10-13,18-22H2,1H3;
InChI Key
JDNAVZKVTWHWKB-UHFFFAOYSA-N;
Storage
2-8°C
Complexity
480
Covalently-Bonded Unit Count
1
Exact Mass
404.263g/mol
Heavy Atom Count
29
Monoisotopic Mass
404.263g/mol
Rotatable Bond Count
5
Topological Polar Surface Area
0A^2
Undefined Atom Stereocenter Count
1
Application
Cy-cBRIDP serves as a highly versatile ligand utilized in a variety of palladium-catalyzed reactions. It is particularly effective in facilitating asymmetric synthesis through Takasago Ligands and Complexes. The product excels in promoting the coupling of aryl halides, including notable processes such as the Miyaura-Suzuki, Buchwald-Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions. Furthermore, Cy-cBRIDP plays a crucial role in the palladium-catalyzed Suzuki-Miyaura coupling of aryl boronic acids and is pivotal in the Buchwald-Hartwig aryl amination reaction, showcasing its broad applicability in complex organic synthesis.
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