CAS 98014-14-3 cis-Dichlorobis(2,2'-bipyridine)ruthenium(II)

Synonyms

cis-Bis(2,2'-bipyridine)dichlororuthenium(II) hydrate, 97%; cis-Bis(2,2-bipyridine)dichlororuthenium(ii)hydrate; cis-Bis(2,2 inverted exclamation marka-bipyridine)dichlororuthenium(II) hydrate; cis-Dichlorobis(2,2'-bipyridine)ruthenium(II), 97%; VP14897;

IUPAC Name

dichlororuthenium;2-pyridin-2-ylpyridine;hydrate;

Molecular Weight

502.361g/mol

Molecular Formula

C20H18Cl2N4ORu;

Canonical SMILES

C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.O.Cl[Ru]Cl;

InChI

InChI=1S/2C10H8N2.2ClH.H₂O.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;/h2*1-8H;2*1H;1H2;/q;;;;;+2/p-2;

InChI Key

XBOQABVNRXVAKI-UHFFFAOYSA-L;

Complexity

123

Covalently-Bonded Unit Count

Exact Mass

501.99g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

501.99g/mol

Rotatable Bond Count

Topological Polar Surface Area

52.6A^2

Application

cis-Dichlorobis(2,2'-bipyridine)ruthenium(II), a dark green to black powder, serves a critical role in the synthesis of various ruthenium complexes. Notably, it facilitates the modification of gold nanoparticle surfaces for the detection of cysteine through selective luminescence. Beyond this, it is instrumental in creating ruthenium complexes aimed at designing photochromic molecular switches and forming self-assembling supramolecular systems. Additionally, its hydrated form has been utilized in preparing [Ru(2,2'-bipyridine)3]2+(PF6-)2 and as an intermediate in developing nanocomposite junctions with gold nanoparticles.

March 17, 2025

Versatile Catalyst for Advanced Research Applications

Excellent for synthesizing ruthenium complexes. We used it to modify gold nanoparticles, enhancing selective luminescence for cysteine detection. Its versatility is invaluable in developing nanocomposite junctions and photochromic switches. Highly recommend for research!