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Chromium(II) chloride

Catalog Number
ACM10049055-3
Product Name
Chromium(II) chloride
CAS
10049-05-5
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Synonyms
Chromium dichloride
Molecular Weight
122.9
Molecular Formula
CrCl2
Boiling Point
1120 °C
Melting Point
824 °C
Purity
99%+
Density
2.9 g/mL at 25 °C (lit.)
Solubility
Soluble in water
Appearance
Off-white to green-gray powder
Storage
Store below +30 °C
Application
Chromium(II) chloride serves multiple vital roles in various industrial and chemical processes due to its versatile properties and reactivity. This compound, appearing as a white-to-blue crystalline solid, primarily functions as a reducing agent, particularly in the reduction of alpha-haloketones to ketones, epoxides to olefins, chloroimides to imines, and aromatic aldehydes to alcohols. Its reactivity, especially in vapor-phase co-reductions, facilitates the formation of intermetallic compounds with significant thermoelectric, magnetic, and oxidation-resistance properties, proving its utility in creating advanced materials. Additionally, it acts as a catalyst in organic synthesis and is a critical component in the Nozaki-Hiyama-Kishi and Takai olefination reactions, forming key intermediates such as vinyl iodides. Beyond these applications, chromium(II) chloride is used in chromium plating, aiding in the production of a range of industrial materials. Despite its numerous benefits, handling this compound requires caution due to its environmental impact and reactive nature, especially when exposed to oxidizing agents, as violent reactions or hazardous byproducts like hydrogen gas might occur. Thus, chromium(II) chloride represents a valuable yet sensitive tool in both chemical manufacturing and advanced research fields.
December 25, 2024

Exceptional Reducing Agent for Organic Synthesis

Chromium(II) chloride from Alfa Chemistry is indispensable in our lab. As a reducing agent, it seamlessly converts alpha-haloketones to ketones, proving essential for complex reaction processes. Reliable, powerful performance enhanced our research outcomes significantly.

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