Molecular Weight
925.23
Molecular Formula
C54H45ClP3Rh
Purity
Metal purity 99.95
Appearance
red
Color Form
crystalline
Empirical Formula
Rh(PPh3)3Cl
Metal Content
11
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- Chlorotris(triphenylphosphine)rhodium(I)
Chlorotris(triphenylphosphine)rhodium(I)
Catalog Number
ACM14694952-2
Product Name
Chlorotris(triphenylphosphine)rhodium(I)
CAS
14694-95-2
Application
Chlorotris(triphenylphosphine)rhodium(I) serves a multifaceted role as a catalyst in various chemical reactions owing to its versatility and efficiency under mild conditions. Known for its distinctive magenta crystals, it acts as a homogeneous hydrogenation catalyst, prominently catalyzing the hydrogenation of alkenes, which is a key process in organic synthesis. It is also employed in the catalytic hydroboration of alkenes with agents such as catecholborane and pinacolborane, and supports the selective 1,4-reduction of α,β-unsaturated carbonyl compounds. This compound is invaluable in reactions like the decarbonylation of aldehydes, regio- and stereoselective allylic substitution reactions, and the Heck-type reaction with α,β-unsaturated esters. Furthermore, it facilitates alkyne hydro-phosphorylation, alkyne arylation, as well as allylic alcohol-olefin coupling. Additional applications include its use in synthesizing terminal alkenes from ketones, the Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones, and the reductive deprotection of silyl groups, underscoring its broad utility in advanced organic chemistry.
February 21, 2025
Exceptional Catalyst for Diverse Applications
Chlorotris(triphenylphosphine)rhodium(I) from Alfa Chemistry excels in facilitating efficient Suzuki and hydrogenation reactions. In our research, its ease of use and versatility in catalysis significantly advanced our project's outcomes. Highly recommended for synthetic applications.
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