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Chlorotris(triphenylphosphine)cobalt(I)

Chlorotris(triphenylphosphine)cobalt(I)

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Catalog Number

ACM26305759-2

Product Name

Structure

CAS

26305-75-9

Product Overview
Usage

Synonyms

CoCl(Ph3P)3

IUPAC Name

cobalt;triphenylphosphane;chloride;

Molecular Weight

881.24

Molecular Formula

[(C6H5)3P]3CoCl

Canonical SMILES

Cl[Co].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.ClH.Co/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChI Key

RHNBOEDTKLKUEB-UHFFFAOYSA-M

Melting Point

135-139 °C (dec.) (lit.)

Purity

0.97

Appearance

powder

Complexity

202

Covalently-Bonded Unit Count

Exact Mass

880.175g/mol

Formal Charge

-1

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

880.175g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

Application

Chlorotris(triphenylphosphine)cobalt(I) is primarily used as a stoichiometric reducing agent that facilitates the radical dimerization of halogenated organic molecules, including the reductive radical dimerization of 3-haloindoline derivatives. Additionally, it plays a key role in cobalt(I)-catalyzed, stereoselective olefination processes involving alkylzinc reagents and aryl aldehydes. The compound is also utilized in cobalt-catalyzed, asymmetric addition reactions of silylacetylene to 1,1-disubstituted allenes, showcasing its versatility in various chemical transformations.

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CAS
Size
Purity
Price
Quantity
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26305-75-9
-
0.97
-
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