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Chlorobis(ethylene)rhodium(I) Dimer

Catalog Number
ACM12081162-2
Product Name
Chlorobis(ethylene)rhodium(I) Dimer
Structure
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CAS
12081-16-2
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Synonyms
Chlorobis(ethylene)rhodium(I) Dimer;12081-16-2;micro-Dichlorotetraethylene dirhodium(I);Dichlorotetra(ethylene)dirhodium(I);QPOCZCJMFQWGSP-UHFFFAOYSA-L;AKOS015964160;
IUPAC Name
ethene;rhodium;dichloride;
Molecular Weight
388.927g/mol
Molecular Formula
C8H16Cl2Rh2-2;
Canonical SMILES
C=C.C=C.C=C.C=C.[Cl-].[Cl-].[Rh].[Rh];
InChI
InChI=1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/p-2;
InChI Key
QPOCZCJMFQWGSP-UHFFFAOYSA-L;
Storage
-20°C
Covalently-Bonded Unit Count
8
EC Number
235-145-0
Exact Mass
387.874g/mol
Formal Charge
-2
H-Bond Acceptor
2
Heavy Atom Count
12
Monoisotopic Mass
387.874g/mol
Topological Polar Surface Area
0A^2
Application
Chlorobis(ethylene)rhodium(I) Dimer is a red-brown powder primarily utilized as a precursor for the rhodium(I) norbornadiene catalyst, which plays a crucial role in the asymmetric 1,4-addition of arylboronic acids to cyclic enones. In addition, it serves as a vital organic intermediate and is instrumental in catalyzing the dimerization of ethylene to 1-butene. Furthermore, this compound is essential in the preparation of homogeneous catalysts, highlighting its versatility and significance in chemical synthesis processes.
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