NAVIGATION
- Home
- Products
- Metal Catalysts
- Iridium Catalysts
- Chlorobis(cyclooctene)iridium(I) Dimer
Chlorobis(cyclooctene)iridium(I) Dimer
Catalog Number
ACM12246514-3
Product Name
Chlorobis(cyclooctene)iridium(I) Dimer
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/12246-51-4.gif)
CAS
12246-51-4
Synonyms
MFCD00213465; CJJIQMGSHWWMCK-XFCUKONHSA-L; J-004808; chlorobis(cyclooctene)-iridium(I) dimer; Di-mu-chlorotetrakis(cyclooctene)diiridium(I); Chlorobis(cyclooctene)iridium(I)dimer; 12246-51-4;
IUPAC Name
cyclooctene;iridium;dichloride;
Molecular Weight
896.134g/mol
Molecular Formula
C32H56Cl2Ir2-2;
Canonical SMILES
C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.[Cl-].[Cl-].[Ir].[Ir];
InChI
InChI=1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/p-2/b4*2-1-;;;;;
InChI Key
CJJIQMGSHWWMCK-XFCUKONHSA-L;
Complexity
62.1
Covalently-Bonded Unit Count
8
Defined Bond Stereocenter Count
4
Exact Mass
894.299g/mol
Formal Charge
-2
H-Bond Acceptor
2
Heavy Atom Count
36
Monoisotopic Mass
896.302g/mol
Topological Polar Surface Area
0A^2
Application
Chlorobis(cyclooctene)iridium(I) Dimer serves as a versatile catalyst with a range of applications in organic synthesis. It facilitates isomerization-hydroboration reactions when combined with nido-carboranyldiphosphine as a stabilizing ligand. Additionally, it plays a crucial role in the hydrogen peroxide oxidation of hydroxamic acids, leading to subsequent hetero Diels-Alder cycloaddition reactions. This compound is also employed in the immobilization of organic functional groups onto solid supports via vinylsilane coupling reactions. Its catalytic properties are further utilized in alkylation reactions, the Guerbet reaction, and allylic amination reactions, particularly within DNA-diene-iridium(I) hybrid systems. Moreover, it is an effective catalyst for asymmetric hydroamination reactions, making it an invaluable tool in modern synthetic chemistry.
- CAS
- Size
- Purity
- Price
- Quantity
- Order
- 12246-51-4
- -
- -
- -
-
- +
-
Online Inquiry
※ Please kindly note that our products are for research use only.
Tris(2,4-pentanedionato)iridium(III)
(15635-87-7)
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
(12148-71-9)
Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)
(92220-65-0)
Tris[2-phenylpyridinato-C2,N]iridium(III)
(94928-86-6)
Iridium(III) chloride hydrate
(14996-61-3)
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
(2030437-92-2)
