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Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-H8-binap)]Cl

Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-H8-binap)]Cl

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Catalog Number

ACM944451278

Product Name

Structure

CAS

944451-27-8

Product Overview
Usage

Synonyms

(R)-RuCl[p-cymene)(H8-BINAP)]Cl;(S)-RuCl[(p-cymene)(H8-BINAP)]Cl;944451-27-8;Chloro[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-5,5 inverted exclamation marka,6,6 inverted exclamation marka,7,7 inverted exclamation marka,8,8 inverted exclamation marka-octahydro-1,1 inverted exclamation marka-binaphthyl](p-cymene)ruthenium(II) chloride;Chloro[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-5,5 inverted exclamation marka,6,6 inverted exclamation marka,7,7 inverted exclamation marka,8,8 inverted exclamation marka-octahydro-1,1 inverted exclamation marka-binaphthyl](p-cymene)ruthenium(II) chloride;

IUPAC Name

chlororuthenium(1+);[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene;chloride;

Molecular Weight

936.9

Molecular Formula

C54H54Cl2P2Ru

Canonical SMILES

CC1=CC=C(C=C1)C(C)C.C1CCC2=C(C1)C=CC(=C2C3=C(C=CC4=C3CCCC4)P(C5=CC=CC=C5)C6=CC=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

InChI

InChI=1S/C44H40P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;/h1-12,19-26,29-32H,13-18,27-28H2;4-8H,1-3H3;2*1H;/q;+2/p-2

InChI Key

RDVYAXZMACLMGN-UHFFFAOYSA-L

Melting Point

>100 °C

Purity

98%+

Appearance

Powder

Storage

2-8°C

Complexity

885

Covalently-Bonded Unit Count

Exact Mass

936.212121

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

936.212121

Rotatable Bond Count

Topological Polar Surface Area

0 Å²

Application

The primary purpose of Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride is to serve as a highly effective catalyst in asymmetric reactions, crucial for producing enantiomerically pure compounds. This complex, part of the Takasago Ligands and Complexes series, facilitates the formation of chiral molecules, which are essential in various applications, including the pharmaceutical industry, where the specificity and activity of enantiomers can significantly impact therapeutic outcomes. By leveraging its robust chiral environment and catalytic efficiency, the product stands out as a valuable tool in the development of innovative and sustainable synthetic processes.

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