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- Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride
Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride
Catalog Number
ACM944451290-2
Product Name
Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/944451-29-0.gif)
CAS
944451-29-0
Molecular Weight
916.77
Molecular Formula
C48H42Cl2O4P2Ru
Color Form
solid
Empirical Formula
[RuCl(p-cymene)(S)-SEGPHOS)]Cl
Metal Content
11
Application
The purpose of Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride is to serve as a highly active and enantioselective catalyst, particularly in the asymmetric hydrogenation of functionalized ketones. This catalyst excels in achieving efficient hydrogenation of α-substituted-β-alkyl-β-ketoesters, often utilizing dynamic kinetic resolution processes. To activate the cymene complexes present in this compound, a slightly elevated temperature is needed, ensuring enhanced performance and selectivity in complex chemical reactions.
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