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Chloro(pyridine)bis(dimethylglyoximato)cobalt(III)

Chloro(pyridine)bis(dimethylglyoximato)cobalt(III)

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Catalog Number

ACM23295321

Product Name

Structure

CAS

23295-32-1

Product Overview
Usage

Synonyms

NSC175756;NSC-175756;23295-32-1;

IUPAC Name

chlorocobalt(1+);(NE)-N-[(3E)-3-hydroxyiminobutan-2-ylidene]hydroxylamine;piperidin-1-ide;

Molecular Weight

403.71

Molecular Formula

C13H19ClCoN5O4

Canonical SMILES

CC(=NO)C(=NO)C.CC(=NO)C(=NO)C.C1CC[N-]CC1.Cl[Co+];

InChI

InChI=1S/C5H10N.2C4H8N2O2.ClH.Co/c1-2-4-6-5-3-1;2*1-3(5-7)4(2)6-8;;/h1-5H2;2*7-8H,1-2H3;1H;/q-1;;;;+2/p-1/b;2*5-3+,6-4+;;;

InChI Key

HMXQEQFAVFPUEP-DVTASQICSA-M;

Melting Point

235 °C

Purity

95%+

Complexity

349

Covalently-Bonded Unit Count

Defined Bond Stereocenter Count

Exact Mass

410.101g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

410.101g/mol

NSC Number

175756

Topological Polar Surface Area

131A^2

Application

Chloro(pyridine)bis(dimethylglyoximato)cobalt(III) serves as a versatile catalyst, facilitating various chemical reactions with its unique properties. This compound is specifically designed to enhance photocatalytic hydrogen generation from water when exposed to visible light, promoting sustainable energy solutions. Additionally, it is an efficient catalyst in the Doetz benzannulation reaction, proton electroreduction reactions, and radical heterocyclization reactions. Furthermore, it aids in the preparation of Mannich base analogues, showcasing its utility in diverse synthetic processes.

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CAS
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Purity
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23295-32-1
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95%+
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