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Chloro(dimethylsulfide)gold(I)

Chloro(dimethylsulfide)gold(I)

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Catalog Number

ACM29892373

Product Name

Structure

CAS

29892-37-3

Product Overview
Usage

Synonyms

Chlorogold;methylsulfanylmethane

IUPAC Name

chlorogold;methylsulfanylmethane;

Molecular Weight

294.55

Molecular Formula

C2H6AuClS

Canonical SMILES

CSC.Cl[Au]

InChI

InChI=1S/C2H6S.Au.ClH/c1-3-2;/h1-2H3;1H/q;+1;/p-1

InChI Key

YQALRAGCVWJXGB-UHFFFAOYSA-M

Melting Point

160 °C

Purity

98%

Appearance

Powder

Storage

0-10°C

Complexity

4.8

Covalently-Bonded Unit Count

Exact Mass

293.954444

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

293.954444

Rotatable Bond Count

Topological Polar Surface Area

25.3 Å²

Application

Chloro(dimethylsulfide)gold(I) serves as a versatile precursor in the synthesis of various gold(I) catalysts, offering significant utility in organic synthesis. This compound is particularly effective in catalyzing the intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild conditions. Additionally, it is used in the synthesis of other important gold complexes, including chloro(trimesitylphosphine)gold(I), gold(I) N-heterocyclic carbene (NHC) complexes, bis(carbene)gold(I) complexes of ferrocenyl compounds, and gold(I) acetylide complexes. Furthermore, it acts as a foundational gold(I) precursor for developing more advanced gold catalysts, which are crucial in converting propargyl sulfoxides into α-thioenones.

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CAS
Size
Purity
Price
Quantity
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29892-37-3
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98%
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