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Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II)

Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II)

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Catalog Number

ACM71397336-1

Product Name

Structure

CAS

71397-33-6

Product Overview
Usage

Synonyms

71397-33-6;Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II);Chloro(cyclopentadienyl)[bis(diphenylphosphino)-methane]ruthenium(II);MFCD07782002;C30H27ClP2Ru;1085AC;SC10203;Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II), 97%;

IUPAC Name

chlororuthenium;cyclopenta-1,3-diene;diphenylphosphanylmethyl(diphenyl)phosphane;

Molecular Weight

586.014g/mol

Molecular Formula

C30H27ClP2Ru;

Canonical SMILES

C1=C[CH]C=C1.C1=CC=C(C=C1)P(CP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Ru];

InChI

InChI=1S/C25H22P2.C5H5.ClH.Ru/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;1-2-4-5-3-1;;/h1-20H,21H2;1-5H;1H;/q;;;+1/p-1;

InChI Key

NFGZGIRSDQBCFT-UHFFFAOYSA-M;

Complexity

365

Covalently-Bonded Unit Count

Exact Mass

586.032g/mol

Heavy Atom Count

Monoisotopic Mass

586.032g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

Application

Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II) serves as an efficient catalyst for various chemical transformations, notably including the anti-Markovnikov hydration of terminal alkynes. This versatile compound facilitates a range of reactions such as β-alkylation with primary alcohols, cyclization of terminal alkynals to form cycloalkenes, and the electrochemical oxidation of methanol. Additionally, it is effective in promoting the hydration of 1-alkynes and the isomerization of allylic alcohols, demonstrating its broad utility in synthetic chemistry.

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