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Chloro[2-dicyclohexyl(2',6'-dimethoxybiphenyl)phosphine] gold(I)

Chloro[2-dicyclohexyl(2',6'-dimethoxybiphenyl)phosphine] gold(I)

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Catalog Number

ACM854045957

Product Name

CAS

854045-95-7

Product Overview
Usage

Synonyms

MFCD21608486;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)gold(I);854045-95-7;

IUPAC Name

chlorogold;dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphanium;

Molecular Weight

643.962g/mol

Molecular Formula

C26H36AuClO2P+;

Canonical SMILES

COC1=C(C(=CC=C1)OC)C2=CC=CC=C2[PH+](C3CCCCC3)C4CCCCC4.Cl[Au];

InChI

InChI=1S/C26H35O2P.Au.ClH/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;;/h9-11,16-21H,3-8,12-15H2,1-2H3;;1H/q;+1;;

InChI Key

PPKGSOIFMDZUMX-UHFFFAOYSA-N;

Complexity

454

Covalently-Bonded Unit Count

Exact Mass

643.181g/mol

Formal Charge

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

643.181g/mol

Rotatable Bond Count

Topological Polar Surface Area

18.5A^2

Application

Chloro[2-dicyclohexyl(2',6'-dimethoxybiphenyl)phosphine] gold(I) serves as a highly-efficient and regio-selective catalyst with several applications. It plays a crucial role in facilitating the selective carbonyl migration in alkynyl-substituted indole-3-carboxamides. Additionally, this catalyst is employed in the hydroarylation and aromatization of arene-diynes, as well as in the selective hydration of substituted alkynes at room temperature, enhancing reaction efficiency and precision.

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